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Rubber Polymers

    EXXON Halogenated Butyl Rubber (CIIR+BIIR)


As EXXON Bromobutyl and EXXON Chlorobutyl both contain the predominantly saturated backbone of Butyl, these polymers have many of the attributes of the Butyl polymers:

  • Low permeability to air, gases and moisture
  • Vibration damping
  • Low glass transition temperature
  • Resistance to ageing and to weathering from atmospheric exposure
  • Wide vulcanization versatility
  • Fast cure rates
  • Processing safety: no nitrosamines or nitrosamines precursors
Halobutyls display additional covulcanization with general purpose high-unsaturation elastomers, like natural rubber, polybutadiene, and styrene-butadiene rubber, while maintaining the mostly saturated backbone structure.

EXXON Bromobutyl and EXXON Chlorobutyl standard 75 lb. bales are provided with either of these wraps:

  • EVA: Inclusion film. Melting Point @ 93 to 96°C
  • RFU: Blue colored Removable Film Unit or strippable film
  Chemical Resistance Guide

EXXON Bromobutyl Polymers

EXXON Bromobutyl is structurally similar to EXXON Chlorobutyl and, like Chlorobutyl it has a broader vulcanization latitude than butyl due to its reactive functionality.

In relation to Chlorobutyl, Bromobutyl provides an additional level of crosslinking reactivity based upon its lower C-Br bond energy, compared to the C-Cl bond. This results in compounds with faster cure rates that can utilize a wider assortment of curative systems. As a result, Bromobutyl provides an even higher level of co-curing compatibility with general purpose elastomers than Chlorobutyl.

  Mooney Viscosity Cure Rate
view specifications  view MSDS    request a sample    EXXON BROMOBUTYL 2211 EVA 32±5 Fast
view specifications  view MSDS    request a sample    EXXON BROMOBUTYL 2222 EVA 32±5 Regular
view specifications  view MSDS    request a sample    EXXON BROMOBUTYL 2244 EVA 46±5 Fast
view specifications  view MSDS    request a sample    EXXON BROMOBUTYL 2255 EVA 46±5 Regular

EXXON Chlorobutyl Polymers

Chlorobutyl can be vulcanized with certain curative systems to provide improved properties at elevated temperatures in comparison to Butyl. It also enables a degree of covulcanization with general purpose rubbers which Butyl cannot achieve.

Due to the relative reactivity of carbon-halogen bonds, Chlorobutyl reacts more slowly than Bromobutyl, so it possesses a more predictive cure response with additional scorch and processing safety, and less sensitivity to mixing, processing, and storage conditions.
  Mooney Viscosity  
view specifications  view MSDS    request a sample    EXXON CHLOROBUTYL 1066 EVA 38±5  
view specifications  view MSDS    request a sample    EXXON CHLOROBUTYL 1066 RFU 38±5  
view specifications  view MSDS    request a sample    EXXON CHLOROBUTYL 1068 EVA 50±5  

EXXON is a trademark of ExxonMobil Chemical Corporation.


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   R.T. Vanderbilt Company, Inc.
 30 Winfield Street
 Norwalk, CT   06856
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